|Before the adjustments|
|After the adjustment|
PS and added two layers, in Layer 1 I clicked on the Channel Mixer adjustment layer and ticked the monochrome box and then upped the contrast a little to keep the eyes, the hair and facial features. Then on layer 2 I added a Gaussian Blur and a radius of aound 20 pixels and added a blend to this layer called Overlay and after any opacity changes I ended up with the left image. Finally I added a brown colored Vignette which made the subject stand out even more.